Rhodium-catalyzed intramolecular C-H insertion of alpha-aryl-alpha-diazo ketones.

ABSTRACT: Direct diazo transfer proceeds smoothly with alpha-aryl ketones. The derived alpha-aryl-alpha-diazo ketones cyclize efficiently with Rh catalysis to give the corresponding alpha-aryl cyclopentanones.

SUBMITTER: Taber DF 

PROVIDER: S-EPMC3248813 | biostudies-literature | 2007 Apr

REPOSITORIES: biostudies-literature