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Cis-Bis(4-methyl-piperazine-1-carbo-dithio-ato-?S,S')bis-(pyridine-?N)cadmium.

ABSTRACT: In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexa-coordinated by two N atoms from two pyridine ligands and by four S atoms from two dithio-carbamate ligands in a distorted octa-hedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4?(1)° with that of the pyridine ring.

SUBMITTER: Valarmathi P

PROVIDER: S-EPMC3254348 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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cis-Bis(4-methyl-piperazine-1-carbo-dithio-ato-κS,S')bis-(pyridine-κN)cadmium.

Valarmathi P P Thirumaran S S Kapoor Kamini K Gupta Vivek K VK Kant Rajni R

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexa-coordinated by two N atoms from two pyridine ligands and by four S atoms from two dithio-carbamate ligands in a distorted octa-hedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring. ...[more]

PMID: 22259382

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