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1-Ferrocenyl-3-(4-methyl-anilino)propan-1-one.

ABSTRACT: In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo-penta-dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro-symmetric dimers via N-H⋯O hydrogen bonds. In addition, C-H⋯O and C-H⋯N contacts stabilize the crystal packing.

SUBMITTER: Leka Z

PROVIDER: S-EPMC3274942 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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1-Ferrocenyl-3-(4-methyl-anilino)propan-1-one.

Leka Zorica Z Novaković Sladjana B SB Stevanović Dragana D Bogdanović Goran A GA Vukićević Rastko D RD

Acta crystallographica. Section E, Structure reports online 20120131 Pt 2

In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo-penta-dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro-symmetric dimers via N-H⋯O hydrogen bonds. In addition, C-H⋯O a ...[more]

PMID: 22346889

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