Space group revsion of the triclinic polymorph of salicyl-aldehyde azine.

ABSTRACT: The structure of the title compound, C(14)H(12)N(2)O(2) {systematic name: 2,2'-[hydrazinediylidenebis(methanylyl-idene)]diphen-ol}, has already been determined in the triclinic space group P[Formula: see text] with Z = 4 [El-Medani, Aboaly, Abdalla & Ramadan (2004 ▶). Spectrosc. Lett.37, 619-632]. However, the correct space group should be P2(1)/c with Z = 4. This structure is a new polymorph of the already known monoclinic polymorph of salicyladehyde azine, which crystallizes in space group P2(1)/n with Z = 2. The benzene rings form a dihedral angle of 46.12 (9)°. Two intramolucular O-H⋯N hydrogen bonds occur.

SUBMITTER: Saeed A 

PROVIDER: S-EPMC3274948 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature