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2,3,4,6-Tetra-O-acetyl-β-d-galacto-pyrano-syl butyrate.


ABSTRACT: The title compound, C(18)H(26)O(11), was synthesized by a condensation reaction of 2,3,4,6-tetra-O-acetyl-α-d-galactopyranosyl bromide and butyric acid. The acet-oxy-methyl and butyrate groups are located on the same side of the pyran ring, showing the β configuration for the d-glycosyl ester; the butyl group adopts an extend conformation, the C-C-C-C torsion angle being 179.1 (7)°. In the crystal, the mol-ecules are linked by weak C-H⋯O hydrogen bonds.

SUBMITTER: Cui YL 

PROVIDER: S-EPMC3275009 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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2,3,4,6-Tetra-O-acetyl-β-d-galacto-pyrano-syl butyrate.

Cui Yan-Li YL   Xu Ming-Han MH   Mao Jian-Wei JW   Yu Yong-Ping YP  

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2


The title compound, C(18)H(26)O(11), was synthesized by a condensation reaction of 2,3,4,6-tetra-O-acetyl-α-d-galactopyranosyl bromide and butyric acid. The acet-oxy-methyl and butyrate groups are located on the same side of the pyran ring, showing the β configuration for the d-glycosyl ester; the butyl group adopts an extend conformation, the C-C-C-C torsion angle being 179.1 (7)°. In the crystal, the mol-ecules are linked by weak C-H⋯O hydrogen bonds. ...[more]

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