Cu(I)/O2 chemistry using a β-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity.

ABSTRACT: A Cu(I) complex, LCu(CH(3)CN), was prepared and characterized, where L(-) is a sterically unencumbered β-diketiminate ligand, the deprotonated version of 4-(2,2-dimethylhydrazino)dimethylhydrazone-3-penten-2-one (LH). Analysis of FTIR spectra of the products of the reaction of LCu(CH(3)CN) with CO indicate that L(-) is strongly electron donating, and support an equilibrium in solution between monomeric and dimeric forms with terminal and bridging CO ligands, respectively. Low temperature oxygenation of LCu(CH(3)CN) generated a bis(μ-oxo)tricopper complex with a S = 1 [Cu(3)O(2)](3+) core that was identified on the basis of UV-vis (λ(max) (ε, M(-1) cm(-1) per Cu) = 328 (10700), 420 (1500), 590 (835) nm) and X-band electron paramagnetic resonance (EPR) spectroscopy (Δm(s) = 2 transition at 1

SUBMITTER: Gupta AK 

PROVIDER: S-EPMC3278800 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature