Trimethyl-sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca-borate.

ABSTRACT: In the asymmetric unit of the title salt, C(3)H(9)S(+)·CH(2)B(11)FI(10)N(-) or (CH(3))(3)S[1-H(2)N-6-F-closo-1-CB(11)I(10)], both ions lie in general positions. The anion is perfectly ordered and so the positions of the C-NH(2) vertex and the fluorine substituent are clearly assigned. The relatively short C-N bond length may be inter-preted in terms of a very electron deficient {closo-1-CB(11)} cluster.

SUBMITTER: Finze M 

PROVIDER: S-EPMC3295433 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature