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Cu(I)-catalyzed (11)C carboxylation of boronic acid esters: a rapid and convenient entry to (11)C-labeled carboxylic acids, esters, and amides.


ABSTRACT: Rapid and direct: the carboxylation of boronic acid esters with (11)CO(2) provides [(11)C]carboxylic acids as a convenient entry into [(11)C]esters and [(11)C]amides. This conversion of boronates is tolerant to diverse functional groups (e.g., halo, nitro, or carbonyl).

SUBMITTER: Riss PJ 

PROVIDER: S-EPMC3299884 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature