Transmission eigenvalue distributions in highly conductive molecular junctions.

ABSTRACT:

Background

The transport through a quantum-scale device may be uniquely characterized by its transmission eigenvalues τ(n). Recently, highly conductive single-molecule junctions (SMJ) with multiple transport channels (i.e., several τ(n) > 0) have been formed from benzene molecules between Pt electrodes. Transport through these multichannel SMJs is a probe of both the bonding properties at the lead-molecule interface and of the molecular symmetry.

Results

We use a many-body theory that properly describes the complementary wave-particle nature of the electron to investigate transport in an ensemble of Pt-benzene-Pt junctions. We utilize an effective-field theory of interacting π-electrons to accurately model the electrostatic influence of the leads, and we develop an ab initio

SUBMITTER: Bergfield JP 

PROVIDER: S-EPMC3304317 | biostudies-literature | 2012

REPOSITORIES: biostudies-literature