{4,4',6,6'-Tetra-bromo-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}copper(II).

ABSTRACT: In the title compound, [Cu(C(19)H(16)Br(4)N(2)O(2))], the Cu(II) ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) ion is distorted square-planar, which is defined by the N(2)O(2) donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an inter-molecular π-π inter-action [centroid-centroid distance = 3.8891 (18) Å].

SUBMITTER: Kargar H 

PROVIDER: S-EPMC3343805 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature