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Dibromidobis(pyrazine-2-carboxamide-κN(4))zinc.


ABSTRACT: The title complex, [ZnBr(2)(C(5)H(5)N(3)O)(2)], shows crystallographic mirror symmetry with the Zn atom and the two bromine ligands located on the mirror plane. The Zn atom is four-coordinated in a distorted tetra-hedral fashion by two N atoms from two pyrazine-2-carboxamide ligands and two Br atoms. Only one of the amino H atoms is involved in an N-H⋯O hydrogen bond. The crystal packing is further stabilized by weak N-H⋯N and C-H⋯O inter-actions.

SUBMITTER: Shirvan SA 

PROVIDER: S-EPMC3343906 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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Dibromidobis(pyrazine-2-carboxamide-κN(4))zinc.

Shirvan Sadif A SA   Haydari Dezfuli Sara S  

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4


The title complex, [ZnBr(2)(C(5)H(5)N(3)O)(2)], shows crystallographic mirror symmetry with the Zn atom and the two bromine ligands located on the mirror plane. The Zn atom is four-coordinated in a distorted tetra-hedral fashion by two N atoms from two pyrazine-2-carboxamide ligands and two Br atoms. Only one of the amino H atoms is involved in an N-H⋯O hydrogen bond. The crystal packing is further stabilized by weak N-H⋯N and C-H⋯O inter-actions. ...[more]

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