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Di-μ-benzoato-κ(3)O,O':O;κ(3)O:O,O'-bis-[aqua-(nitrato-κO)(1,10-phenanthroline-κ(2)N,N')lead(II)].

ABSTRACT: The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π stacking between neighboring phen ligands, with a centroid-centroid distance of 3.557 (3) Å.

SUBMITTER: Cheng Y 

PROVIDER: S-EPMC3343907 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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Di-μ-benzoato-κ(3)O,O':O;κ(3)O:O,O'-bis-[aqua-(nitrato-κO)(1,10-phenanthroline-κ(2)N,N')lead(II)].

Cheng Yuanzheng Y   Yan Fang F   Shi Weiwei W   Zhang Liping L  

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4

The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by π-π stacking between neighboring phen ligands, with a centroid-centroid distance of 3.557 (3) Å. ...[more]

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