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2-Amino-3-chloro-5-nitro-benzamide.

ABSTRACT: The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C-C-C-O = 34.2 (5)°] whereas the nitro group is almost co-planar [O-N-C-C = 4.0 (5)°] with the ring. Intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonds occur. In the crystal, the mol-ecules are linked by N-H⋯O hydrogen bonds, generating layers propagating in the ab plane.

SUBMITTER: Wardell JL

PROVIDER: S-EPMC3343961 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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2-Amino-3-chloro-5-nitro-benzamide.

Wardell James L JL Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120310 Pt 4

The amide group in the title compound, C(7)H(6)ClN(3)O(3), is significantly twisted out of the plane of the benzene ring [C-C-C-O = 34.2 (5)°] whereas the nitro group is almost co-planar [O-N-C-C = 4.0 (5)°] with the ring. Intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonds occur. In the crystal, the mol-ecules are linked by N-H⋯O hydrogen bonds, generating layers propagating in the ab plane. ...[more]

PMID: 22590042

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