Bis(2,2'-bipyridyl-κ(2)N,N')bis-(dicyanamido-κN)manganese(II).

ABSTRACT: In title complex, [Mn(C(2)N(3))(2)(C(10)H(8)N(2))(2)], the Mn(II) ion is coordinated in a slightly distorted octa-hedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)°. The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies.

SUBMITTER: Wang H 

PROVIDER: S-EPMC3344319 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature