Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-Plus couplings.

ABSTRACT: High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.

SUBMITTER: Krasovskiy A 

PROVIDER: S-EPMC3365517 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature