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Bis(dicyanamido-κN)tetra-kis-(pyridine-κN)nickel(II).


ABSTRACT: In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3379085 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis(dicyanamido-κN)tetra-kis-(pyridine-κN)nickel(II).

Wöhlert Susanne S   Wriedt Mario M   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6


In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors. ...[more]

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