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N,N'-Dibutyl-N,N,N',N'-tetra-methyl-ethane-1,2-diaminium μ-oxido-bis-[trichloridoferrate(III)].

ABSTRACT: The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C-H⋯Cl and C-H⋯O inter-actions.

SUBMITTER: Narhi SM 

PROVIDER: S-EPMC3379087 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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N,N'-Dibutyl-N,N,N',N'-tetra-methyl-ethane-1,2-diaminium μ-oxido-bis-[trichloridoferrate(III)].

Närhi Sari M SM   Kostamo Jatta J   Asikkala Janne J   Oilunkaniemi Raija R   Laitinen Risto S RS  

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C-H⋯Cl and C-H⋯O inter-actions. ...[more]

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