Unknown

Dataset Information

0

Poly[(μ(3)-benzene-1,3-dicarboxyl-ato-κ(4)O(1):O(1'):O(3),O(3'))bis-(pyridine-κN)cobalt(II)].

ABSTRACT: In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands. The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis. C-H⋯O hydrogen bonds are observed in the tape and between the tapes.

SUBMITTER: Xie F 

PROVIDER: S-EPMC3379094 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[(μ(3)-benzene-1,3-dicarboxyl-ato-κ(4)O(1):O(1'):O(3),O(3'))bis-(pyridine-κN)cobalt(II)].

Xie Fengxia F   Zhang Dan D   Zhang Xinxin X  

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands. The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis. C-H⋯O hydrogen bonds are observed in the tape and between the tapes. ...[more]

Similar Datasets

Unknown Bis(μ-pyridine-2,5-dicarboxyl-ato)-κN,O:O;κO:N,O-bis-[aqua-(2,2'-bipyridine-κN,N')cobalt(II)] dihydrate.
| S-EPMC3051640 | biostudies-literature
Unknown Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.
| S-EPMC3051631 | biostudies-literature
Unknown Poly[tetra-aqua-bis-(μ(3)-benzene-1,3-di-carboxyl-ato-κO:O':O'')bis-(μ(2)-benzene-1,3-dicarboxyl-ato-κO,O':O'')[μ(2)-1,4-bis-(1,2,4-triazol-1-yl)butane-κN:N']tetra-zinc(II)].
| S-EPMC3050338 | biostudies-literature
Unknown catena-Poly[bis-[(1,10-phenanthroline)iron(II)]-bis-(μ-5-carboxy-benzene-1,3-dicarboxyl-ato)].
| S-EPMC2967865 | biostudies-literature
Unknown Bis(μ-pyridine-2,4-dicarboxyl-ato)-κN,O:O;κO:N,O-bis-[triaqua-magnesium(II)].
| S-EPMC3008092 | biostudies-literature
Unknown [(Pyridine-2,6-dicarboxyl-ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl-ato)-[bis-(ethyl-enediamine)-copper(II)]-μ-(pyridine-2,6-dicarboxyl-ato)-[(pyridine-2,6-dicarboxyl-ato)copper(II)] ethyl-enediamine monosolvate tetra-hydrate.
| S-EPMC3379149 | biostudies-literature
Unknown catena-Poly[[[aqua-(pyridine-2,6-dicarboxyl-ato N-oxide-κO,O)cobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'] dihydrate].
| S-EPMC2959606 | biostudies-literature
Unknown Poly[propane-1,3-diammonium [cuprate(II)-bis-(μ(2)-pyridine-2,3-dicarboxyl-ato)] trihydrate].
| S-EPMC2960456 | biostudies-literature
Unknown Poly[[tetra-aqua-bis-(μ(3)-pyridine-2,6-dicarboxyl-ato)(μ(2)-pyridine-2,6-dicarboxyl-ato)dilanthanum(III)] dihydrate].
| S-EPMC3200968 | biostudies-literature
Unknown Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cobaltate(II) penta-hydrate.
| S-EPMC3099797 | biostudies-literature