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Aqua-bis-[N'-(1,3-dithio-lan-2-ylidene)-2-hy-droxy-benzohydrazidato(0.5-)-?(2)N',O]sodium(I).

ABSTRACT: The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule. The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis. Intra-molecular N-H?O hydrogen bonds occur. Mol-ecules pack as discrete units and the crystal packing is stabilized by strong O-H?O hydrogen bonds, which give rise to chains along [010]; the chains are inter-linked by strong O-H?O hydrogen bonds.

SUBMITTER: Bouchameni C

PROVIDER: S-EPMC3379147 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Aqua-bis-[N'-(1,3-dithio-lan-2-ylidene)-2-hy-droxy-benzohydrazidato(0.5-)-κ(2)N',O]sodium(I).

Bouchameni Chahra C Beghidja Chahrazed C Beghidja Adel A Boutebdja Mehdi M

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule. The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis. Intra-molecular N-H⋯O hydrogen bonds occur. Mol-ecules pack as discrete units and the crystal packing is stabilized by st ...[more]

PMID: 22719368

Similar Datasets

Poly[[nona-aqua-bis-(μ-5-hy-droxy-benzene-1,3-di-carboxyl-ato)(5-hy-droxy-benzene-1,3-di-carboxyl-ato)dicerium(III)] hexa-hydrate].

Project description:In the title coordination polymer, {[Ce2(C8H4O5)3(H2O)9]·6H2O} n , the asymmetric unit is formed by two Ce(III) atoms, three 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands, nine coordinating water mol-ecules and six water mol-ecules of crystallization. The two Ce(III) atoms are bridged by 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands acting in a bis-bidentate coordination mode, generating infinite chains along [101]. Both independent metal atoms are nine-coordinated, one by four O atoms from the carboxyl-ate groups of two bridging 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands and five O atoms from water mol-ecules, generating a tricapped trigonal-prismatic geometry. The coordination around the second Ce(III) atom is similar, except that one of the water mol-ecules is replaced by an O atom from an additional 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligand acting in a monodentate coordination mode and forming a capped square-anti-prismatic geometry.

| S-EPMC4011209 | biostudies-literature

Poly[μ2-aqua-aqua-[μ3-N-butyl-N-(2-hy-droxy-ethyl)di-thio-carbamato-κ(3) O,O':S]sodium].

Project description:In the title compound, [Na(C7H14NOS2)(H2O)2] n , the Na(I) cation is coordinated by five O atoms [Na-O = 2.3142 (11)-2.4677 (10) Å] from three aqua and two N-butyl-N-(2-hy-droxy-eth-yl)di-thio-carbamate (L) ligands and one S atom [Na-S = 3.0074 (6) Å] from a third L ligand in a highly distorted octa-hedral geometry. Two aqua ligands related by an inversion center bridge two Na(I) cations, and each L ligand coordinates three Na(I) cations, leading to a layered arrangement aligned parallel to the bc plane. Inter-molecular O-H⋯S hydrogen bonds are observed in the inner part of each polymeric layer; these are packed along the a axis and held together by weak van der Waals forces.

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N-[(E,Z)-1,3-Diphenyl-prop-2-enyl-idene]-N'-(1,3-dithio-lan-2-yl-idene)hydrazine.

Project description:Mol-ecules of the title compound, C(18)H(16)N(2)S(2), exist as the (2E, 1'Z)-isomer. The 1,3-dithiol-ane ring has an envelope conformation; the atoms of the C-C bond are disordered over two positions with occupancies of 0.47 (7) and 0.53 (7). The structure exhibits inter-molecular C-H⋯S and C-H⋯π(arene) hydrogen bonds.

| S-EPMC2961686 | biostudies-literature

Di-aqua-bis-[2-(2-hy-droxy-eth-yl)pyridine-κ(2) N,O]cobalt(II) dichloride.

Project description:In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the Co(II) cation, located on an inversion center, is N,O-chelated by two hy-droxy-ethyl-pyridine ligands and coordinated by two water mol-ecules in a distorted O4N2 octa-hedral geometry. In the crystal, the Cl(-) anions link with the complex cations via O-H⋯Cl hydrogen bonds, forming a three-dimensional supra-molecular architecture. π-π stacking is observed between the pyridine rings of adjacent mol-ecules [centroid-centroid distance = 3.5810 (11) Å].

| S-EPMC3793682 | biostudies-literature

3-(1,3-Dithio-lan-2-yl-idene)-1-phenyl-pyridine-2,4(1H,3H)-dione.

Project description:The title compound, C(14)H(11)NO(2)S(2), was synthesized by reaction of 2-(1,3-dithio-lan-2-yl-idene)-3-oxo-N-phenyl-butanamide with N,N'-dimethyl-formamide dimethyl acetal in N,N'-dimethyl-formamide. The mol-ecule exhibits a V-shaped conformation in the crystal, with a dihedral angle of 65.9 (2)° between the benzene and pyridine rings. In the crystal. C-H⋯O and C-H⋯S interactions are observed. Two C atoms of the dithiolane ring are disordered with occupancies in the ratio 0.541 (13)/0.459 (13).

| S-EPMC2969332 | biostudies-literature

3,9-Dimethyl-2,3-dihydro-spiro-[carb-az-ole-1,2'-[1,3]dithio-lan]-4(9H)-one.

Project description:The title compound, C16H17NOS2, consists of a carbazole skeleton with methyl and dithiol-ane groups as substituents. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.02 (11)°. The cyclo-hexenone ring has a twisted conformation, while the dithiol-ane ring adopts an envelope conformation with one of the CH2 C atoms at the flap. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains nearly parallel to the c axis. These hydrogen bonds together with weak C-H⋯π inter-actions link the molecules into a three-dimensional supramolecular network.

| S-EPMC3629639 | biostudies-literature

2-(3-Eth-oxy-2-hy-droxy-benz-ylidene)-N-phenyl-hydrazinecarboxamide.

Project description:The title compound, C(16)H(17)N(3)O(3), exists in the E configuration with respect to the azomethine double bond. The mol-ecule is close to planar, with a dihedral angle of 6.7 (1)° between the aromatic rings. The phenolic O atom functions as donor and acceptor by forming intramolec-ular O-H⋯O and inter-molecular N-H⋯O hydrogen bonds, respectively. Two-dimensional packing is fashioned through an inter-molecular hydrogen bonding network in an offset manner.

| S-EPMC3247376 | biostudies-literature

Methyl 3-(2-hy-droxy-benzyl-idene)-2-methyl-dithio-carbazate.

Project description:In the title compound, C(10)H(12)N(2)OS(2), the thione and S-methyl groups are syn. An intra-molecular bifurcated O-H⋯(S,N) hydrogen bond occurs.

| S-EPMC3344635 | biostudies-literature

[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions between the aromatic rings [centroid-centroid distance = 3.816 (3) Å] link the mol-ecules into centrosymmetric dimers.

| S-EPMC3212120 | biostudies-literature

catena-Poly[[{bis-[tetra-aqua-(2-hy-droxy-3,4-dioxocyclo-but-1-en-1-olato-?O)bariumstrontium(0.35/0.65)]di-?-aqua}-bis-(?-2-hy-droxy-4-oxocyclo-but-1-ene-1,3-diolato-?O:O)] monohydrate].

Project description:The title structure, {[Ba(0.71)Sr(1.29)(C(4)HO(4))(4)(H(2)O)(10)]·H(2)O}(n), is built from dimers of edge-sharing monocapped square anti-prisms [(Ba/Sr)O(3)(H(2)O)(6)], in which barium and strontium are statistically disordered [ratio 0.353?(8):0.647?(8)] on the same crystallographic site. Such dimers are connected via bidentate hydrogen squarate groups [HC(4)O(4)](-), leading to chains that propagate along the b axis. Inter- and intra-molecular O-H?O hydrogen bonds maintain the crystal packing through a three-dimensional network.

| S-EPMC3051722 | biostudies-literature

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