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2-Amino-N'-phenyl-benzohydrazide.


ABSTRACT: In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N-H⋯N hydrogen bonds, forming R(4) (4)(20) rings, and resulting in the formation of a two-dimensional network lying parallel to (010). The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].

SUBMITTER: Kesternich V 

PROVIDER: S-EPMC3379416 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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2-Amino-N'-phenyl-benzohydrazide.

Kesternich Víctor V   Gahona Paulo P   Pérez-Fehrmann Marcia M   Brito Iván I   López-Rodríguez Matías M  

Acta crystallographica. Section E, Structure reports online 20120523 Pt 6


In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N-H⋯N hydrogen bonds, forming R(4) (4)(20) rings, and resulting in the formation of a two-dime  ...[more]

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