Field effects induce bathochromic shifts in xanthene dyes.
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ABSTRACT: There is ongoing interest in near-infrared (NIR) absorbing and emitting dyes for a variety of biomedical and materials applications. Simple and efficient synthetic procedures enable the judicious tuning of through-space polar (field) effects as well as low barrier hydrogen bonding to modulate the HOMO-LUMO gap in xanthene dyes. This affords unique NIR-absorbing xanthene chromophores.
SUBMITTER: Sibrian-Vazquez M
PROVIDER: S-EPMC3384756 | biostudies-literature | 2012 Jun
REPOSITORIES: biostudies-literature
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