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(2,2'-Bipyrimidine-κ(2)N(1),N(1'))diiodidopalladium(II).

ABSTRACT: In the title complex, [PdI(2)(C(8)H(6)N(4))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis iodide anions. The nearly planar bpym ligand [maximum deviation = 0.053 (3) Å] is slightly inclined to the least-squares plane of the PdI(2)N(2) unit [maximum deviation = 0.055 (2) Å], making a dihedral angle of 3.9 (2)°. In the crystal, pairs of complex mol-ecules are assembled by inter-molecular C-H⋯N hydrogen bonds into dimers. Intra-molecular C-H⋯I hydrogen bonds are also observed.

SUBMITTER: Ha K

PROVIDER: S-EPMC3393225 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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(2,2'-Bipyrimidine-κ(2)N(1),N(1'))diiodidopalladium(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title complex, [PdI(2)(C(8)H(6)N(4))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis iodide anions. The nearly planar bpym ligand [maximum deviation = 0.053 (3) Å] is slightly inclined to the least-squares plane of the PdI(2)N(2) unit [maximum deviation = 0.055 (2) Å], making a dihedral angle of 3.9 (2)°. In the crystal, pairs of complex mo ...[more]

PMID: 22807793

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