Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN(4))propan-1-one]bis-(thio-cyanato-κN)copper(II).

ABSTRACT: The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(-) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent mol-ecules occupy the axial positions with long Cu⋯S distances [3.0495 (10) and 3.1045 (9) Å] and complete the overall distorted octahedral coordination sphere. Weak inter-molecular C-H⋯O hydrogen bonds are present.

SUBMITTER: Cai H 

PROVIDER: S-EPMC3414160 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature