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Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes.


ABSTRACT: A highly effective silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.

SUBMITTER: Turkmen YE 

PROVIDER: S-EPMC3415592 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature