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5-Amino-3-eth-oxy-1,8,8-trimethyl-2-aza-bicyclo-[2.2.2]octa-2,5-diene-4,6-dicarbo-nitrile.

ABSTRACT: The title 2-aza-bicyclo-[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol-ecules with similar conformations in the asymmetric unit. In each mol-ecule, the three six-membered rings adopt boat conformations. The mol-ecules exist in the enamine form. In the crystal, mol-ecules are linked by N-H?O and N-H?N hydrogen bonds into a two-dimensional network parallel to the ab plane.

SUBMITTER: Chantrapromma S 

PROVIDER: S-EPMC3435638 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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5-Amino-3-eth-oxy-1,8,8-trimethyl-2-aza-bicyclo-[2.2.2]octa-2,5-diene-4,6-dicarbo-nitrile.

Chantrapromma Suchada S   Suwunwong Thitipone T   Ruanwas Pumsak P   Boonnak Nawong N   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20120801 Pt 9

The title 2-aza-bicyclo-[2.2.2]octa-2,5-diene derivative, C(14)H(18)N(4)O, crystallized out with two independent mol-ecules with similar conformations in the asymmetric unit. In each mol-ecule, the three six-membered rings adopt boat conformations. The mol-ecules exist in the enamine form. In the crystal, mol-ecules are linked by N-H⋯O and N-H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane. ...[more]

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