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N-(2,4-Dichloro-phen-yl)-1,3-thia-zol-2-amine.

ABSTRACT: In the title mol-ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia-zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol-ecules are joined into dimers with an R(2) (2)(8) ring motif by pairs of N-H⋯N hydrogen bonds. These dimers are linked by C-H⋯Cl inter-actions into layers parallel to (011). The thia-zole rings form columns along the c-axis direction, with a centroid-centroid separation of 3.8581 (9) Å, indicating π-π inter-actions. An intra-molecular C-H⋯S contact also occurs.

SUBMITTER: Babar A

PROVIDER: S-EPMC3435722 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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N-(2,4-Dichloro-phen-yl)-1,3-thia-zol-2-amine.

Babar Ayesha A Munawar Munawar Ali MA Tahir M Nawaz MN Ullah Fateh F Tariq Muhammad Ilyas MI

Acta crystallographica. Section E, Structure reports online 20120815 Pt 9

In the title mol-ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia-zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol-ecules are joined into dimers with an R(2) (2)(8) ring motif by pairs of N-H⋯N hydrogen bonds. These dimers are linked by C-H⋯Cl inter-actions into layers parallel to (011). The thia-zole rings form columns along the c-axis direction, with a centroid-centroid separation of 3.8581 (9) Å, indicating π-π inter-actions. An intra-molecular C-H⋯S conta ...[more]

PMID: 22969593

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