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4-Meth-oxy-2-{(E)-[(thio-phen-2-yl)methyl-imino]-meth-yl}phenol.

ABSTRACT: The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol-imine tautomeric form and reveals an intra-molecular O-H⋯N hydrogen bond involving the hy-droxy group and the imino N atom, forming an S(6) ring. The mol-ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C-H⋯O and C-H⋯π inter-actions.

SUBMITTER: Kantar EN

PROVIDER: S-EPMC3435828 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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4-Meth-oxy-2-{(E)-[(thio-phen-2-yl)methyl-imino]-meth-yl}phenol.

Kantar Esen Nur EN Köysal Yavuz Y Macit Mustafa M Er Ebru E Soylu Mustafa Serkan MS

Acta crystallographica. Section E, Structure reports online 20120831 Pt 9

The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol-imine tautomeric form and reveals an intra-molecular O-H⋯N hydrogen bond involving the hy-droxy group and the imino N atom, forming an S(6) ring. The mol-ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C-H⋯O and C-H⋯π inter-actions. ...[more]

PMID: 22969674

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