Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺.

ABSTRACT: Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.

SUBMITTER: Olsen MT 

PROVIDER: S-EPMC3465568 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature