Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis-(triphenyl-phosphane-κP)copper(I) methanol monosolvate.

ABSTRACT: In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra-hedral, defined by two P atoms of two triphenyl-phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol-ecules and the methanol solvent mol-ecules are connected via N-H⋯O and O-H⋯I hydrogen bonds, forming a chain along [010]. An intra-molecular N-H⋯I hydrogen bond is also observed.

SUBMITTER: Jiang YH 

PROVIDER: S-EPMC3470167 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature