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Dichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

ABSTRACT: In the title compound, [CoCl(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.745 (3) Å] are present in the crystal.

SUBMITTER: Akbarzadeh Torbati N

PROVIDER: S-EPMC3515097 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Dichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

Akbarzadeh Torbati Niloufar N Rezvani Ali Reza AR Saravani Hamideh H

Acta crystallographica. Section E, Structure reports online 20121006 Pt 11

In the title compound, [CoCl(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.745 (3) Å] are present in the crystal. ...[more]

PMID: 23284324

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