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Poly[(?(3)-hydrogenphosphato)(4H-1,2,4-triazole-?N(1))zinc].

ABSTRACT: The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2-) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H?O and O-H?O hydrogen bonds between the phosphate groups and the triazole ligands.

SUBMITTER: Aitenneite H 

PROVIDER: S-EPMC3515161 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Poly[(μ(3)-hydrogenphosphato)(4H-1,2,4-triazole-κN(1))zinc].

Aitenneite Hafid H   El Bouari Abdeslam A   Sebti Said S   Saadi Mohamed M   El Ammari Lahcen L   Adil Karim K  

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11

The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2-) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of  ...[more]

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