Dataset Information

Composition and fate of gas and oil released to the water column during the Deepwater Horizon oil spill.

ABSTRACT: Quantitative information regarding the endmember composition of the gas and oil that flowed from the Macondo well during the Deepwater Horizon oil spill is essential for determining the oil flow rate, total oil volume released, and trajectories and fates of hydrocarbon components in the marine environment. Using isobaric gas-tight samplers, we collected discrete samples directly above the Macondo well on June 21, 2010, and analyzed the gas and oil. We found that the fluids flowing from the Macondo well had a gas-to-oil ratio of 1,600 standard cubic feet per petroleum barrel. Based on the measured endmember gas-to-oil ratio and the Federally estimated net liquid oil release of 4.1 million barrels, the total amount of C(1)-C(5) hydrocarbons released to the water column was 1.7 10(11) g. The endmember gas and oil compositions then enabled us to study the fractionation of petroleum hydrocarbons in discrete water samples collected in June 2010 within a southwest trending hydrocarbon-enriched plume of neutrally buoyant water at a water depth of 1,100 m. The most abundant petroleum hydrocarbons larger than C(1)-C(5) were benzene, toluene, ethylbenzene, and total xylenes at concentrations up to 78 μg L(-1). Comparison of the endmember gas and oil composition with the composition of water column samples showed that the plume was preferentially enriched with water-soluble components, indicating that aqueous dissolution played a major role in plume formation, whereas the fates of relatively insoluble petroleum components were initially controlled by other processes.

SUBMITTER: Reddy CM

PROVIDER: S-EPMC3528605 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Composition and fate of gas and oil released to the water column during the Deepwater Horizon oil spill.

Reddy Christopher M CM Arey J Samuel JS Seewald Jeffrey S JS Sylva Sean P SP Lemkau Karin L KL Nelson Robert K RK Carmichael Catherine A CA McIntyre Cameron P CP Fenwick Judith J Ventura G Todd GT Van Mooy Benjamin A S BA Camilli Richard R

Proceedings of the National Academy of Sciences of the United States of America 20110718 50

Quantitative information regarding the endmember composition of the gas and oil that flowed from the Macondo well during the Deepwater Horizon oil spill is essential for determining the oil flow rate, total oil volume released, and trajectories and fates of hydrocarbon components in the marine environment. Using isobaric gas-tight samplers, we collected discrete samples directly above the Macondo well on June 21, 2010, and analyzed the gas and oil. We found that the fluids flowing from the Macon ...[more]

PMID: 21768331

Similar Datasets

Project description:Burning and flaring of oil and gas following the 2010 Deepwater Horizon (DWH) oil spill generated high airborne concentrations of fine particulate matter (PM2.5). Neurological effects of PM2.5 have been previously reported, but this relationship has received limited attention in the context of oil spills. We evaluated associations between burning-related PM2.5 and prevalence of self-reported neurological symptoms during, and 1-3 years after, the DWH disaster cleanup. For 9914 DWH disaster responders in the Gulf Long-term Follow-up Study who worked on the water, we examined aggregate outcomes (central nervous system [CNS; dizziness, sweating, palpitations, nausea, or migraine/severe headache] and peripheral nervous system [PNS; tingling/numbness in extremities, blurred vision, or stumbling] symptoms) and individual symptoms (CNS and PNS symptoms, plus insomnia, vomiting, seizures, and fatigue). We estimated PM2.5 concentrations via Gaussian plume dispersion models and linked these to detailed DWH cleanup work histories. We used log-binomial regression to estimate adjusted prevalence ratios (PR) and 95% confidence intervals, accounting for age, race, ethnicity, and sex, and DWH disaster-related co-exposures to benzene, toluene, ethylbenzene, xylene, and n-hexane (BTEX-H). We examined effect measure modification by age, race, smoking, and BTEX-H exposure. During the disaster, 34% of participants experienced at least one symptom (23% CNS, 12% PNS); 1-3 years later, 30% did (19% CNS, 17% PNS). Evidence of associations with PM2.5 was most consistent for CNS symptoms (PR range: 1.17 to 1.51), although we did not observe exposure-response trends. For PNS, PR ranged from 0.96 to 1.84. Associations with PM were more apparent among those with lower BTEX-H exposure and among older workers. We found some evidence of an association between burning-related PM2.5 and prevalence of neurologic symptoms during the DWH disaster response and 1-3 years later. Understanding these relationships can inform responses to future disasters to better protect human health.

Dataset Information

Composition and fate of gas and oil released to the water column during the Deepwater Horizon oil spill.

Publications

Composition and fate of gas and oil released to the water column during the Deepwater Horizon oil spill.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets