Long-range anion relay chemistry (LR-ARC): a validated ARC tactic.

ABSTRACT: The design, synthesis, and validation of linchpins for Anion Relay Chemistry (ARC) capable of iterative silyl group migrations have been achieved. This tactic permits "long-range" relocation of negative charge across space, to generate reactive distal nucleophilic centers for both alkylation and palladium-catalyzed coupling reactions.

SUBMITTER: Sanchez L 

PROVIDER: S-EPMC3528832 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature