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Acetonyltriphenyl-phospho-nium nitrate.

ABSTRACT: Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing.

SUBMITTER: Diop T 

PROVIDER: S-EPMC3569822 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Acetonyltriphenyl-phospho-nium nitrate.

Diop Tidiane T   Diop Libasse L   Kučeráková Monika M   Dušek Michal M  

Acta crystallographica. Section E, Structure reports online 20130131 Pt 2

Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing. ...[more]

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