Bis[(E)-3-(4-meth-oxy-phen-yl)prop-2-enoato]triphenyl-anti-mony(V) benzene monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic mol-ecule and one benzene mol-ecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal-bipyramidal environment with the carboxyl-ate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb⋯O inter-actions, one of the C-Sb-C angles is widened to 140.19 (6)°.

SUBMITTER: Andreev PV 

PROVIDER: S-EPMC3588489 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature