Unknown

Dataset Information

0

Stevioside methanol tetra-solvate.


ABSTRACT: Stevioside is a naturally occurring diterpenoid glycoside in Stevia rebaudiana Bertoni. The title compound, C38H60O18·4CH3OH, crystallized as its methanol tetrasolvate. Stevioside consists of an aglycone steviol (a tetra-cyclic diterpene in which the four-fused-ring system consists of three six-membered rings and one five-membered ring) and a sugar part (three glucose units). A weak intra-molecular O-H?O hydrogen bond occurs. In the crystal, the methanol mol-ecules participate in a two-dimensional hydrogen-bonded network parallel to b axis with the sugars and together they form a hydrophilic tunnel which encloses the lipophilic part of the molecule.

SUBMITTER: Wu Y 

PROVIDER: S-EPMC3588499 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

Stevioside methanol tetra-solvate.

Wu Yunshan Y   Rodenburg Douglas L DL   Ibrahim Mohamed A MA   McChesney James D JD   Avery Mitchell A MA  

Acta crystallographica. Section E, Structure reports online 20130220 Pt 3


Stevioside is a naturally occurring diterpenoid glycoside in Stevia rebaudiana Bertoni. The title compound, C38H60O18·4CH3OH, crystallized as its methanol tetrasolvate. Stevioside consists of an aglycone steviol (a tetra-cyclic diterpene in which the four-fused-ring system consists of three six-membered rings and one five-membered ring) and a sugar part (three glucose units). A weak intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, the methanol mol-ecules participate in a two-dimension  ...[more]

Similar Datasets

| S-EPMC4647381 | biostudies-literature
| S-EPMC2960063 | biostudies-literature
| S-EPMC3089318 | biostudies-literature
| S-EPMC3007071 | biostudies-literature
| S-EPMC2977439 | biostudies-literature
| S-EPMC2977324 | biostudies-literature
| S-EPMC4120636 | biostudies-literature
| S-EPMC3007521 | biostudies-literature