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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.

ABSTRACT: Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

SUBMITTER: Smith SM

PROVIDER: S-EPMC3601746 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.

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