Catena-Poly[[bis-(2-meth-oxy-aniline-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].
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ABSTRACT: The structure of the title compound, [Cd(NCS)2(C7H9NO)2] n , consists of cadmium-thio-cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio-cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa-hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth-oxy-aniline ligands. The crystal structure is stabilized by intra-layer N-H⋯S hydrogen bonds.
SUBMITTER: Chemli R
PROVIDER: S-EPMC3647823 | biostudies-literature | 2013 May
REPOSITORIES: biostudies-literature
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