Unknown

Dataset Information

Catena-Poly[[bis-(2-meth-oxy-aniline-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].


ABSTRACT: The structure of the title compound, [Cd(NCS)2(C7H9NO)2] n , consists of cadmium-thio-cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio-cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa-hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth-oxy-aniline ligands. The crystal structure is stabilized by intra-layer N-H⋯S hydrogen bonds.

SUBMITTER: Chemli R 

PROVIDER: S-EPMC3647823 | biostudies-literature | 2013 May

REPOSITORIES: biostudies-literature