Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones.

ABSTRACT: A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out.

SUBMITTER: Alcaide B 

PROVIDER: S-EPMC3678844 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature