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15-Meth-oxy-14,15-di-hydro-andranginine.

ABSTRACT: The title polycyclic alkaloid, C22H26N2O3, an indole derivative obtained from Melodinus yunnanensis, comprises three chiral C atoms and crystallizes as a racemate. Its seven-membered heterocyclic ring has a twisted conformation, with the N atom within the plane of the indole moiety and with two adjacent C atoms deviating in opposite directions from its plane by 0.756 (3) (methyl-ene C) and -0.802 (3) Å (methine C). In the crystal, pairs of N-H⋯O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.

SUBMITTER: Wang DL

PROVIDER: S-EPMC3684921 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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15-Meth-oxy-14,15-di-hydro-andranginine.

Wang Dian-Lei DL Cai Xiang-Hai XH Huang Peng P Huang He-Ping HP

Acta crystallographica. Section E, Structure reports online 20130504 Pt 6

The title polycyclic alkaloid, C22H26N2O3, an indole derivative obtained from Melodinus yunnanensis, comprises three chiral C atoms and crystallizes as a racemate. Its seven-membered heterocyclic ring has a twisted conformation, with the N atom within the plane of the indole moiety and with two adjacent C atoms deviating in opposite directions from its plane by 0.756 (3) (methyl-ene C) and -0.802 (3) Å (methine C). In the crystal, pairs of N-H⋯O hydrogen bonds connect the mol-ecules into centros ...[more]

PMID: 23795023

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