Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.

ABSTRACT: Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond.

SUBMITTER: Jiang M 

PROVIDER: S-EPMC3743347 | biostudies-literature | 2013 May

REPOSITORIES: biostudies-literature