Dataset Information

(3R,6R,4'S,8'R,3''R,6''R)-3,3''-Diisopropyl-6,6''-dimethyl-2',6'-di-phenyl-dispiro-[cyclo-hexane-1,4'-(3,7-dioxa-2,6-di-aza-bicyclo-[3.3.0]octa-ne)-8',1''-cyclo-hexa-ne]-2,2''-dione.

ABSTRACT: The two oxazolidine rings (A and B) of the title compound, C34H44N2O4, display roughly half-chair conformations, which could be described as twisted on the C-O bond. Together, the fused oxazolidine rings have a butterfly shape, with the H atoms attached to the ring junction C atoms in a cis orientation. The cyclo-hexane rings of both p-menthone fragments display chair conformations. The absolute configuration could not be determined from the X-ray diffraction data, but the relative configuration of the stereocentres could be deduced.

SUBMITTER: Ansari A

PROVIDER: S-EPMC3770422 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Dataset Information

(3R,6R,4'S,8'R,3''R,6''R)-3,3''-Diisopropyl-6,6''-dimethyl-2',6'-di-phenyl-dispiro-[cyclo-hexane-1,4'-(3,7-dioxa-2,6-di-aza-bicyclo-[3.3.0]octa-ne)-8',1''-cyclo-hexa-ne]-2,2''-dione.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

(3R*,6R*,4'S*,8'R*,3''R*,6''R*)-3,3''-Diisopropyl-6,6''-dimethyl-2',6'-di-phenyl-dispiro-[cyclo-hexane-1,4'-(3,7-dioxa-2,6-di-aza-bicyclo-[3.3.0]octa-ne)-8',1''-cyclo-hexa-ne]-2,2''-dione.

OmicsDI is part of the ELIXIR infrastructure

Tweets

(3R,6R,4'S,8'R,3''R,6''R)-3,3''-Diisopropyl-6,6''-dimethyl-2',6'-di-phenyl-dispiro-[cyclo-hexane-1,4'-(3,7-dioxa-2,6-di-aza-bicyclo-[3.3.0]octa-ne)-8',1''-cyclo-hexa-ne]-2,2''-dione.