Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides.

ABSTRACT: An orthogonal set of catalyst systems has been developed for the Suzuki-Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.

SUBMITTER: Yang Y 

PROVIDER: S-EPMC3776608 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature