An ion's perspective on the molecular motions of nanoconfined water: a two-dimensional infrared spectroscopy study.

ABSTRACT: The vibrational population relaxation and hydration shell dynamics of the symmetric tricyanomethanide (TCM) anion are investigated in a sodium bis(2-ethylhexyl)sulfosuccinate reverse micelle as a function of the water pool radius. Two-dimensional infrared (IR) spectroscopy in combination with linear absorption and ultrafast IR pump-probe spectroscopy is utilized in this study. Spectroscopic measurements show that the anion has two bands in the 2160-2175 cm(-1) region, each with its own spectroscopic signatures. Analysis of the vibrational dynamics shows that the two vibrational bands are consistent with the anion located either at the interface or in the water pool. The sensitivity of the TCM anion to the environment allows us to unequivocally monitor the vibrational and hydration dynamics

SUBMITTER: Singh PK 

PROVIDER: S-EPMC3785012 | biostudies-literature | 2013 Aug

REPOSITORIES: biostudies-literature