{2-[1-(2-Meth-oxy-6-oxidophenyl-κO (6))ethyl-idene]-N-methyl-hydrazinecarbo-thio-amidato-κ(2) N (2),S}(tri-phenyl-phosphane-κP)palladium(II) ethanol monosolvate.

ABSTRACT: In the title compound, [Pd(C11H13N3O2S)(C18H15P)]·C2H5OH, the Pd(II) atom is tetra-coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio-semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri-phenyl-phosphane group. The five-membered ring adopts a distorted envelope conformation with Pd(II) as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth-oxy-phenyl group is fused to the six-membered ring. Weak C-H⋯O inter-actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing.

SUBMITTER: Anderson BJ 

PROVIDER: S-EPMC3790343 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature