Poly[tetra-methyl-ammonium [tri-μ2-formato-κ(6) O:O'-manganate(II)]].

ABSTRACT: In the title compound, {(C4H12N)[Mn(HCO2)3]} n , the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetra-methyl-ammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C-H⋯O hydrogen bonds with the formate ligands.

SUBMITTER: Han CY 

PROVIDER: S-EPMC3790351 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature