Unknown

Dataset Information

0

Kinetic resolution in asymmetric epoxidation using iminium salt catalysis.

ABSTRACT: The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.

SUBMITTER: Page PC 

PROVIDER: S-EPMC3817536 | biostudies-literature | 2013 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Kinetic resolution in asymmetric epoxidation using iminium salt catalysis.

Page Philip C Bulman PC   Appleby Louise F LF   Chan Yohan Y   Day David P DP   Buckley Benjamin R BR   Slawin Alexandra M Z AM   Allin Steven M SM   McKenzie Michael J MJ  

The Journal of organic chemistry 20130806 16

The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes. ...[more]

Similar Datasets

Unknown Chirality recognition of winding vine-shaped heterobiaryls with molecular asymmetry. Kinetic and dynamic kinetic resolution by Shi's asymmetric epoxidation.
| S-EPMC5786050 | biostudies-literature
Unknown Desymmetrization and Parallel Kinetic Resolution of 1-Ethynylcyclobutanols via Asymmetric Cooperative Gold Catalysis.
| S-EPMC11572530 | biostudies-literature
Unknown Racemic hemiacetals as oxygen-centered pronucleophiles triggering cascade 1,4-addition/Michael reaction through dynamic kinetic resolution under iminium catalysis. Development and mechanistic insights.
| S-EPMC5376714 | biostudies-literature
Unknown Kinetic resolution of indolines by asymmetric hydroxylamine formation.
| S-EPMC8096955 | biostudies-literature
Unknown Use of a robust dehydrogenase from an archael hyperthermophile in asymmetric catalysis-dynamic reductive kinetic resolution entry into (S)-profens.
| S-EPMC2869291 | biostudies-literature
Unknown Iminium Catalysis in Natural Diels-Alderase
| S-EPMC12381789 | biostudies-literature
Unknown Aspartate-catalyzed asymmetric epoxidation reactions.
| S-EPMC2669669 | biostudies-literature
Unknown Dynamic kinetic resolution of α-keto esters via asymmetric transfer hydrogenation.
| S-EPMC3342478 | biostudies-literature
Unknown Asymmetric α-spirocyclopropanation of oxindoles and benzofuranones via dynamic kinetic resolution.
| S-EPMC9814566 | biostudies-literature
Unknown Kinetic resolution of substituted amido[2.2]paracyclophanes via asymmetric electrophilic amination.
| S-EPMC10462673 | biostudies-literature