8-Quinolinolato gallium complexes: iso-selective initiators for rac-lactide polymerization.

ABSTRACT: The synthesis and characterization of a series of 8-quinolinolato gallium complexes is presented, and the complexes are analogous to a series of aluminum complexes previously reported. The complexes have been shown to be active initiators for the ring-opening polymerization of rac-lactide. High degrees of polymerization control are demonstrated, as exemplified by the linear evolution of molecular weight as the polymerization progresses, narrow polydispersity indices, and molecular weights corresponding to those predicted on the basis of initiator concentration. Some of the initiators show iso-selective polymerization of rac-lactide, with Pi = 0.70. The polymerization rates have been monitored, and the pseudo first-order rate constants are compared to those of analogous aluminum compounds.

SUBMITTER: Bakewell C 

PROVIDER: S-EPMC3829202 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature