Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures.

ABSTRACT: The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

SUBMITTER: Baum AE 

PROVIDER: S-EPMC3860832 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature