DABSO-based, three-component, one-pot sulfone synthesis.

ABSTRACT: The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.

SUBMITTER: Deeming AS 

PROVIDER: S-EPMC3883144 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature